Tuesday, September 20, 2022

Identification and Evaluation of best suitable feedstock for Compressed Biogas production




My childhood memories cannot be complete without one of our family friends who loves to ask us tricky questions to us and I personally always fall into his trap. One of the questions is “Which one is more? One kilogram of cotton or One kilogram of iron.” The beauty of the question is that it looks very simple and tempting but one needs to have adequate knowledge about the subject otherwise it will trick you for sure. Over the years in the industry, such questions rather dilemmas never lost their relevance irrespective of innovation in ways of doing things in the recent past.

The compressed biogas (CBG) industry is not alien to such questions. One such question which we would like to elaborate on today is the selection of feedstock quantity. Most of us must have come across many aspirants in the market who want to set up a plant for ABC Ton of waste to CBG plant and they appear to be firm in the ton of waste processing irrespective of its specification and its overall impact on final products. It is not about the capability of the project developer but the area where we need to put our best effort to ensure we select the best mix of raw materials for a sustainable CBG project in a longer duration. For doing so one needs to understand the basic of feedstock and how it get translated to final products mainly CBG. We would be using some of the typical composition of the feedstock with an average yield of gas and then extend the data to some common baseline to evaluate all the feedstock on the same level field.

The feedstocks in consideration are as below and their typical specification is as mentioned in the table. Please don’t go by the values they could be here and there but the trend needs to be captured.

Sr. No

Feedstock

Typical TS

Typical TVS

Avg. Biogas Yield on as is basis (Sm3/MT)

% w/w

% w/w

1

OFMSW

25-30

65-75

80-100

2

Napier Grass

25-30

75-80

120-180

3

Poultry Litter

25-28

70-75

80-100

4

Press Mud

25-30

70-75

80-120

5

Segregated Food Waste

25-30

85-90

110-130

6

Paddy Straw

90-92

70-75

350-400

7

Cow Dung / Farm manure

15-20

55-65

40-50


The yield per MT of as is feedstock varies from 40 to 400 sm3/MT which is the very high range and could be confusing for some for comparison, evaluation and arriving at the right blend for the particular plant under a given set of conditions. In business what works there might not work here so the team needs to be very vigilant when referring the set of feedstock from the particular location/plant in content to some other plant.

When one say a particular feedstock has X yield and some other has Y then what do they actually mean? Let's try to elaborate this further. One can notice that above mentioned feedstock has a varying levels of TS and Moisture content. As biogas generation process only generates biogas which is methane, Carbon dioxide, Hydrogen sulfide etc with saturated moisture by equilibrium. To make it simple the volatile / digestible portion of organic only get converted to biogas and average efficiency of its conversion is typically 55-65% based on the type of reactor assuming stable operating conditions. Generally, total volatile solids fraction is considered to be digestible and the rest is non-digestible portion. Non-digestible is mostly Ash part of it and lignin like hard to digest components. For this evaluation lets consider TVS as a basis then all the feedstock on dry basis looks like as mentioned in the below table.

Sr. No

Feedstock

Typical TS

Typical TVS

TVS

% w/w

% w/w

Kg/DMT

1

OFMSW

30

70

700.0

2

Napier Grass

25

80

800.0

3

Poultry Litter

28

75

750.0

4

Press Mud

30

72

720.0

5

Segregated Food Waste

30

90

900.0

6

Paddy Straw

90

75

750.0

7

Cow Dung / Farm manure

20

65

650.0


  The average volatile solid content of any feedstock is about 750 kg per Dry MT and considering 55 to 65% avg degradation efficiency of TVS the average biogas generation could be 350 sm3/ DMT. If this is to be represented as CBG potential it will look somewhat as below,

Sr. No

Feedstock

Typical TS

Typical TVS

TVS

CBG yield

% w/w

% w/w

Kg/DMT

kg/DMT

1

OFMSW

30

70

700.0

113.3

2

Napier Grass

25

80

800.0

240

3

Poultry Litter

28

75

750.0

128.6

4

Press Mud

30

72

720.0

113.3

5

Segregated Food Waste

30

90

900.0

146.7

6

Paddy Straw

90

75

750.0

155.6

7

Cow Dung / Farm manure

20

65

650.0

90.0


This is only one dimension of yield and as a common logic goes one should use the feedstock with the highest yield and try to avoid the one with the lowest yield, right. But wait let’s try to superimpose the economical viewpoint on this table and see how much each kg of CBG produced cost us for sourcing the feedstock. We have assumed the cost of feedstock as landed cost inside the plant and if some other components which could be site specific will impact either of the value accordingly.

Sr. No

Feedstock

Typical TS

Biogas Yield

CBG Yield

Feedstock Cost

CBG Loading

% w/w

m3/MT as is

kg/ MT as is

Rs/ MT As is

Rs / Kg CBG

1

OFMSW

30

85

34

100

2.9

2

Napier Grass

25

150

60

1000

16.7

3

Poultry Litter

28

90

36

400

11.1

4

Press Mud

30

85

34

300

8.8

5

Segregated Food Waste

30

110

44

100

2.3

6

Paddy Straw

90

350

140

3000

21.4

7

Cow Dung / Farm manure

20

45

18

500

28


There could be cases of higher yield at higher costs, Lower yield at a higher cost, and Moderate yield at average cost of feedstock. This matrix will be project-specific and values will change from project to project but the trend and impact of it need to be evaluated in accordance with the specific projects so that the optimum feedstock mix can be arrived at. The feedstock is a very important aspect of any CBG project as it is on of the highest recurring cost of operation and can be as high as 35 to 40% of the overall operating expenses of the plant. Not only the cost of sourcing the feedstock mix will drive storage and handling requirement, Processing technology and utilities consume mainly power for conversion to CBG. Please note power and feedstock togather controls upto 70% of overall plant operating cost and through full evaluation of it through a systematic evaluation template and method for each plant.

At actuality how much amount could be spared for sourcing feedstock will depend on price of final product realized at the particular site along with the encashment of byproducts. However, looking at the present scenario I will personally be very cautious whenever the feedstock loading on CBG goes beyond INR 15 per kg CBG in the preliminary evaluation and mark red for further detailing.

Please don’t go by the values as these will change its relevance case to case and level of detailing but the overall trend shall not be missed.

The article https://www.linkedin.com/pulse/feedstocks-compressed-natural-gas-production-bharat-kadu/ could be best pre-read for this article.

Saturday, November 27, 2021

Today's Compressed biogas (CBG) is Tomorrow's green hydrogen

 

A developing economy like India Knows the importance of energy as it is the largest resource that will shape our future in the coming years. Looking at fossils import burden and rising prices of fuels in the country will only speed up the drive for renewable fuels like Ethanol, Methanol, ATJ, CBG apart from renewable electricity.

Our strong commitment will lead to more hunger and effort to increase to the production of renewable fuels and energies which will make India clean and self-sufficient to a major extent. The infrastructure is developing at a great pace for the biofuel drive and we have made great progress for liquid and gaseous biofuels. The years to come will witness more robust infrastructure from all aspects apart from production scale, off-take and distribution.

Hydrogen is the fuel of the future and talk of the town in recent past for all good reasons around the globe. India is all set to play a major role in the green hydrogen economy moving forward. At present major section of the industry is focusing on the production of green hydrogen from renewable energy like solar and wind for large scale production. The world green hydrogen industry is also focusing on similar energies and very much aligned to the way India approaches it.

Agriculture is the backbone of the Indian economy and any industry which connect to the ground always had a larger impact on national interest. Doubling farmers income is one of the prime objectives of authorities and most of the national programs have this connection which is our strength.

Biogas to CBG mission was started with this connect in the background in 2018 and going strong. CBG is one of the important biofuels in focus after Ethanol in India at present time. Industry moving very positively to make 5000 CBG plant a reality. To make this happen all part of the industry is playing major roles whether it is technology, engineering, infrastructure, OMC’s, Financial institutions or agriculture teams with a vision for bio-fertilizer.

Once the CBG infrastructure will take a shape across the country alongside the EV boom will become a strong foundation for hydrogen-based transportation. The CBG has methane as a major component and it can be readily converted to hydrogen. These CBG plants will then be all set to transform to decentralized hydrogen generation stations which will fuel our energy and transportation future in years to come. CBG to green hydrogen will be detailed in coming articles soon.  



Friday, June 5, 2020

Tone of refrigeration


A ton of Refrigeration (TR)

A ton of refrigeration (TR)  is a unit of heat extraction capacity of the refrigeration or cooling equipment. Generally, TR is defined as the amount of heat transferred to freeze or melt 1 short ton of ice at 0 deg. C in 24 hours. 

1 TR is approximately equal to 12000 BTU or 3024 Kcal/hr of energy/heat load. 

The heat of the fusion of water is about 335 KJ/kg or 80.01 kCal/kg. 1 short ton is equal to 2000 lb or 907 kg. 

                      

 Example: 1000 kg/hr of air is to be cooled from  45 deg. C to 10 Deg. C in the heat exchanger with chilled water for some process requirement then what will be chiller capacity required. Temp. the difference across the chiller is assumed to be 5 deg. C. The chilling water is pumped through a heat exchanger using a centrifugal pump. The Chiling circuit is as below,
Ans:
TR is the amount of heat to be extracted from the system or process.
Assumption :
1.     Air is 100 % dry at inlet temp.
2.     The system is well insulated and Heat gain from the atmosphere is negligible.

Here cooling duty of the heat exchanger is the amount of heat to be extracted and heat added by a chilling water recirculation pump.

Let's calculate the Chilling duty (Qa) of the heat exchanger.

Qa     = Air Flow rate x Cp of Air x ( Air in temp – Air out Temp)
          = 1000 x 0.24 x ( 45-10 )
          = 8400 Kcal/hr
Qa = 8400/3024 = 2.78 TR ------------------ I

Let's calculate the chilling water flow rate (Mw) for Qa
Chilling water flow rate (Mw)  = Qa /( Cp x ( Chiller temp. Diff.)

Mw = 8400 /(1*5) =
Mw = 1.7 m3/hr ------------------------ II

Pumping power (Shaft power) with about 30-meter liquid head and 30 % pump efficiency is about 0.44 kWh. Assuming worse case that all pumping power  (Qp) will be added to liquid which is about 0.44 kWh i.e. 378 kCal/hr ( 1 kWh = 860 Kcal).
Total heat load on chiller is,
 Qc    = Qa+Qp
          = 8400 + 378
          = 8778 Kcal/ Hr ------------------------------ III
Chiller Capacity =  8778 Kcal/hr i.e. 2.9 TR.

Note:
1.     If air or gas is saturated or has moisture then the heat of condensation will be added to cooling duty to calculate actual chiller capacity.